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MELLUTEL™ PVC-F50

✔ reduce the interfacial tension between vinyl chloride monomer (VCM) and water

✔ prevent the coalescence of VCM droplets at the initial stage of polymerization

✔ prevent coalescence between polymer particles in the later stage of the polymerization process

✔ in the suspension polymerization system, it plays a dual role of dispersion and stability protection

✔ improve glue retention capacity and reduce the average particle size of the resin

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Product Details

Main application

HPMC is one of the main dispersants in PVC industry. During suspension polymerization of vinyl chloride, it can reduce the interfacial tension between vinyl chloride monomer (VCM) and water, and help VCM to be evenly and stably dispersed in the aqueous medium; Prevent the coalescence of VCM droplets at the initial stage of polymerization; Prevent coalescence between polymer particles in the later stage of the polymerization process. In suspension polymerization system, it plays a dual role of dispersion and stability protection. HPMC consumption accounts for 0.025%～0.03% of PVC output.

HPMC is the main dispersant commonly used in PVC production. With the increase of viscosity and the decrease of hydroxypropyl content, the dispersing ability of HPMC weakens and the glue retention ability increases, resulting in the increase of average particle size and apparent density of PVC resin; Increasing the concentration of HPMC can improve its glue retention ability and reduce the average particle size of the resin.

Structural formula

Hydroxypropyl Methylcellulose for PVC

(n～2)/2

OR=-OH、-OCH3、-[OCH2CH(CH3)]nOH or-[OCH2CH(CH3)]OCH3

Specification

Type	60YT	65YT	75YT
Item	HPMC	HPMC	HPMC
Methoxy %	28.0～30.0	27.0～30.0	19.0～24.0
Hydroxypropyl %	7.0～12.0	4.0～7.5	4.0～12.0
Gel temperature ℃	58.0～64.0	62.0～68.0	70.0～90.0
Viscosity mPa.s	50		100
pH			5.0～8.5
Loss on drying		%	≤4.5
Burning residue		%	＜1.0
Whiteness		%	≥80
Transmittance		%	≥90
Bulk density		g/L	400～500

Applied to PVC features

1. during suspension polymerization, reduce the interfacial tension between vinyl chloride monomer (VCM) and water, and help VCM to be evenly and stably dispersed in the aqueous medium.

2. prevent the coalescence of VCM droplets at the initial stage of polymerization.

3. prevent coalescence between polymer particles in the later stage of the polymerization process.

4. in the suspension polymerization system, it plays a dual role of dispersion and stability protection.

5. with the increase of HPMC viscosity and the decrease of hydroxypropyl content, the interfacial tension increases, the dispersion ability decreases, the glue retention ability increases, the average particle size of PVC resin increases, the resin porosity decreases, and the apparent density increases.